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Chemistry 12: College Preparation Unit 5 Self Quiz - 5.7 - 5.11



Modified True/False
Indicate whether the sentence or statement is true or false.  If false, change the identified word or phrase to make the sentence or statement true.
 

 1. 

Every galvanic cell has two electrodes and at least one electrolyte. ____________________

 

 2. 

In a galvanic cell, oxidation occurs at the cathode. ____________________

 

 3. 

In a galvanic cell that involves two metal electrodes, the metal that is higher on the activity series accepts electrons. ____________________

 

 4. 

Anions always move to the anode. ____________________

 

 5. 

Electrons always flow from the cathode to the anode. ____________________

 

 6. 

The salt bridge in a galvanic cell must contain ions that do not react with the other chemicals in the cell. ____________________

 

 7. 

The size of the cell potential depends only on the electrodes that are used to construct the galvanic cell. ____________________

 

 8. 

Given two alkaline dry cells from the same manufacturer, the larger cell will produce more electrical energy. ____________________

 

 9. 

The electrolyte in an alkaline dry cell is acidic. ____________________

 

 10. 

Primary cells can be recharged. ____________________

 

 11. 

The contents of nickel–cadmium batteries are bad for the environment. ____________________

 

Short Answer
 

 12. 

a. Sketch a diagram of a galvanic cell that involves the following two half-cells connected
by a salt bridge.
• half-cell 1: iron nail in a solution of iron(II) sulfate, FeSO4(aq)
• half-cell 2: copper strip in a solution of copper(II) sulfate, CuSO4(aq)
b. What would be a suitable electrolyte for the salt bridge in this cell? Why?
c. Iron is oxidized because it is higher on the activity series than copper.
d. Identify the anode. ____________________
e. Identify the cathode. ______________________
f. Write the anode half-reaction. _________________________________
g. Write the cathode half-reaction. _________________________________
h. Write the overall cell reaction. __________________________________
 

 13. 

In any galvanic cell, the anode and cathode chemicals must remain separate. Explain how they are separated in
a. a laboratory galvanic cell
b. an alkaline dry cell
 

 14. 

The following galvanic cells were constructed using nitrate solutions of the same molar concentration: Mg/Ag, Zn/Ag, Fe/Ag, Cu/Ag. For example, the Mg/Ag galvanic cell consists of
• an anode half-cell: a strip of magnesium in a solution of magnesium nitrate
• a cathode half-cell: a strip of silver in a solution of silver nitrate
a. Use the activity series to predict which cell has the largest cell potential.
b. Which cell has the smallest cell potential?
 

 15. 

Figure 1 shows a simple galvanic cell, made by inserting an inert graphite electrode into an aluminum pop can.

u5sq5-7-11_files/i0170000.jpg

Figure 1
A pop can cell
a. Before the connector is attached to the pop can, the point of contact must be cleaned with sandpaper. Why?
b. What will happen to the cell potential if the graphite electrode is allowed to touch the bottom of the can? Why?
c. How does the thickness of the aluminum change over time?
 

 16. 

Describe how fuel cells differ from primary cells.
 



 
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