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UNIT 5: ELECTROCHEMISTRY

Chapter 10: Electrolytic Cells


p. 741Z
Practice

6. Research and describe some of the variety of uses of aluminum summarized in the exhibition, “Aluminum by design: Jewellery to Jets.”

Aluminum by Design: Jewelry to Jets
Hosted by the Carnegie Museum of Art, this website is devoted to an exhibition that houses examples of the various uses to which aluminum has been put throughout history.


p. 741
Practice

7. Research and describe the newer, ion-exchange membrane cell design for the chlor-alkali process. Include a labelled cell diagram and the function of the membrane. Why is it superior to other designs?

Chlor-Alkali Membrane Cell Process
This group of websites is known as the Chemical Engineers' Resource Page. This site explains the use of the chlor-alkali membrane cell, using easy-to-read text and diagrams.

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p. 742Explore an Issue – Take a Stand: The Case For and Against Chlorine

a. Research the production, storage, transportation, and uses of chlorine and assess one environmental, health, or safety issue.
b. What is the best resolution of the issue you assessed? Present your findings in a way designed to influence decision makers. Include an outline of your findings in your presentation.

Chlorine Saves Lives
Hosted by the Chlorine Chemistry Council, this website explains many everyday uses of chlorine, and contains several links to other websites with information about chlorine. It is a very useful starting point.

Chlorine Bleaches Out Life
The Chlorine Free Products Association represents "companies dedicated to implementing advanced technologies, and/or, groups supporting products free of chlorine chemistry." Some information about its stance can be found on this website in its News page and its online Newsletter.

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p. 744
Practice

13. There are companies that specialize in bronzing baby booties, sports equipment, and keepsakes. Find one and research the service it offers.

a. How does it make a nonconductor like a shoe into an electrode? Which electrode?
b. Briefly describe the process and the approximate costs for typical items.

Caswell Plating

Explore the website for Caswell Plating, a company that provides a wide range of plating kits and plating supplies. There is a tutorial on electroplating on the Plating Kits page of the website (the tutorial requires Flash).

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p. 744
Practice

14. Electroplating industries produce considerable waste that is expensive to manage and an environmental hazard if not treated properly. List four different types of electroplating waste, including potential hazards. Describe some ways companies reduce, recover, and treat electroplating wastes.

Electroplating Shops – Watch Your Waste
This website is sponsored by the U.S. state of Illinois’ Environmental Protection Agency. It provides information for companies and industries involved in electroplating, giving them tips on the laws that apply to them, as well as hints in reducing and preventing pollution.

Reducing Recycling Costs
This website is hosted by the Argonne National Laboratory, which belongs to the U.S. Department of Energy. They have developed a new process for disposing wastes that result from several common electroplating processes.

Pollution Solutions: Metal Finishing
This website from the Office of Waste Management of the University of Missouri provides many tips and strategies that businesses and industries can use to dispose of, and safely use, many metal finishing by-products. The recommendations are very well organized and clearly laid out.

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p. 744
Practice

15. Aluminum cans are widely used for beverages. Write a short report about the production of aluminum cans, including how the can is made, how the top is attached to the can, how the construction of the can has changed since the first model, and the advantages of using recycled aluminum instead of new aluminum.

The Life Cycle of an Aluminum Can
This corporate website will take you through the five major phases in the life of an aluminum can. It uses easy-to-read text along with diagrams and charts in order to explain how most aluminum cans are created, used, and recycled.

Fun Facts on Can History
This website provides some interesting and little-known facts about aluminum can history and recycling. The social history of the aluminum can is actually quite interesting.

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p. 745
Practice – Careers

16. Research one of the careers listed, or another related career that may interest you. Write a report that

a. provides a general description of the work and how it is related to metals;
b. describes the education and training required;
c. outlines the current opportunities in this area, including typical salaries.

Jobs Starting With M
See how many jobs there are that begin with the word, “metal.” This website provides an excellent start for investigating any career.

Occupational Descriptions
This website is provided by the government of Ontario’s Ministry of Education. It contains a vast array of resources that you can use to find job descriptions and qualifications for all sorts of different occupations.

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p. 746
Section 10.2 Questions

11. The loonie replaced the one-dollar bill, which typically wore out in the space of a few months. The Royal Canadian Mint wanted to produce a dollar coin with a richer sheen than the shiny metals used in coins of lower value. Sherritt Gordon of Fort Saskatchewan, AB developed a unique process for plating the loonie coin.

a. Research the production and composition of the loonie.
b. What is the golden “aureate” finish on the loonie? Describe the materials and process for producing the finish.
c. Why did the coin end up with a loon stamped on it?

One Dollar
This website of the Royal Canadian Mint explains the loonie’s significance and history. You can find out not only about what types of design changes have taken place since the loonies was introduced, but you can also find out the technical specifications (actual composition) of the coin.

Westaim’s Aureate
This corporate website promotes the coinage material, aureate, that it manufactures. It discusses the properties of this material and promotes the advantages that this material exhibits.

Electroplated Coinage Technology
This corporate website discusses Westaim’s coin development process. It discusses the development and production of various coinage materials, the operation of its plants, and a brief promotional history of its company.

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p. 761
Chapter 10 Review

19. Plastic components used in the automotive and electronic industries are often electroplated with chromium, nickel, or copper to give them a metallic appearance. The two major challenges for electroplating are to make the surface of the material electrically conductive and to effectively bond the metal to the plastic.

a. How is plastic made electrically conductive?
b. How is the metal bonded to the plastic?
c. What are some of the limitations/problems associated with electroplating plastics?

How We Electroplate
This corporate website explains the process of electroplating, as it relates to Borough’s products and services. A few diagrams are also provided for clarity.

Plastic Plating
This corporate website describes one of the services that the company offers: plastic plating. It uses a few enlargeable photographs and captions to demonstrate its product.


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p. 761
Chapter 10 Review

20. Sludge and wastewater from electroplating processes contain chromium, copper, nickel, and silver, as well as cyanide ions. Sending these metals to landfill or discharging them in wastewater, instead of recycling them, is detrimental to the environment and wasteful of energy. Technologies are being developed to separate and purify these metals, including precipitation, electrolysis, and reverse osmosis. Research one technology designed to reduce the environmental impact of the electroplating industry, and write a short account of how it works.

Water Recycling Costs
This corporate website describes Remco Engineering’s recommendations regarding, and discussion concerning, the various methods that are available for recycling water used in electroplating. It discusses four types of systems, their advantages and disadvantages.

Hexavalent Chromium Waste Treatment
This corporate resource document describes a method available to dispose of hexavalent chromium waste, a carcinogenic chemical that became infamous after the wide coverage it received due to the movie, Erin Brokovich.

Cleaner Production
This New Zealand government website describes an approach that it recommends for businesses and other organizations, called “Cleaner Production.” It describes the advantages of such an approach, and elaborates on government programs that will support any business/organization’s endeavour to place a greater emphasis on the environment.

GE Betz
This website provides links to the various products and services offered by GE Betz, a subsidiary of General Electric, who are “shaping the future of water and process treatment.”

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