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Nelson Education > School > Secondary Science > Chemistry 12 > Student Centre > Web Activities > Chapter 5
 

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UNIT 3: ENERGY CHANGES AND RATES OF REACTION

Chapter 5 – Thermochemistry

 

Practice

p. 300
Question 7

The energy content of foods is sometimes describes as “calories” rather than the SI unit of joules. Physical activity is describe as “burning calories.” Research the answers to the following questions:


a. What are the relationships among a calorie, a Calorie, and a joule?
b. Are calories actually burned? Why is this terminology used?
c. What laboratory methods are used to determine the energy content of foods?

Dietary Calorie versus "Physics" Calorie
This Physlink.com site answers a question regarding the difference between dietary and physical calories.

Fat Calories versus Protein/Carbohydrate Calories
This American Council on Science and Health website contains an article from the Council's e-journal, Priorities. In this article, a medical doctor explains why sometimes calorie-counting may not help predict weight-loss or gain.

Counting Calories
This archived editorial from Foodproductdesign.com discusses several drawbacks to the conventional methods used to count calories, and tackles issues raised by such "supplement" foods as Olestra.

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Section 5.1 Questions

p. 305
Question 7

The bomb calorimeter is a commonly used laboratory apparatus. Research and write a brief report describing the applications of this technology.

The Bomb Calorimeter
This website contains a useful diagram of a typical bomb calorimeter used in a lab and an explanation of how the bomb calorimeter works.

Heats of Combustion of Liquid Hydrocarbon Fuels
This website of the White Sands Test Facility explains the process through which one might determine the heat of combustion of hydrocarbons. It contains many links to other NASA-affiliated websites.

Thermochemistry
This site belongs to a group of private Web sites hosted by Erik Epp, called Erik's Chemistry. It provides an excellent and succinct overview of thermodynamics at a first-year university level.

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Question 8

Hot packs and cold packs use chemical reactions to produce or absorb energy. Write a brief report describing the chemical systems used in these products and their usefulness.

Hot and Cold Reactions
Using basic principles to begin with, this Dartmouth University website explains how exactly it is possible that systems may increase or decrease in temperature independent of their surroundings.

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Sections 5.2 Questions

p. 312
Question 7

The propane refrigerator seems to be a contradiction in terms: the exothermic combustion of a hydrocarbon is used to cool food.


a. Find out how this device functions and what changes in matter occur in its operation.
b. Calculate enthalpy changes expected in a typical example.

How Refrigerators Work
This How Stuff Works website explains the functioning of refrigerators. If you turn to page 5 in the article, you will find an explanation of gas and propane refrigerators, along with a link to a much more detailed website.

The Invention of Freon
This article from About.com explains how Midgely and Kettering invented Freon for General Motors. It also goes on to discuss their other inventions--leaded gasoline and the automobile ignition system.

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Practice

p. 344
Question 2

Nuclear reactors in the United States and Europe use different systems than the CANDU system. Research and make a chart to summarize the similarities and differences among these systems.

The Virtual Nuclear Tourist
This website contains links to an astounding amount of information regarding the world's nuclear power plants.

Safety of Nuclear Power Reactors
This briefing paper from the Uranium Information Centre of Melbourne, Australia discusses several safety issues regarding nuclear power reactors.

The Reactor Engineer's Home Page
This site simply lists a large number of links that are divided into categories like "Professional Organizations," "International Nuclear Agencies," and other useful titles.

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Practice

p. 346
Question 4

Current nuclear power generation uses nuclear fission reactions. Why are fission reactions used instead of fusion reactions? Report on what progress has been made in making nuclear fusion practical as an energy source.

Fusion Power
This article from the BBC News website addresses the potential attainment of fusion power by leading scientists in the United Kingdom.

A Galaxy of Fusion Reactors
This picture of a galaxy is found on the Princeton Plasma Physics Laboratory website, a laboratory that is devoted to making fusion power a reality.

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Section 5.6 Questions

p. 346
Question 2

Research and report on atomic energy in Ontario. Include descriptions of:


a. locations of nuclear facilities;
b. amount of power generated; and
c. advantages and disadvantages of this energy source.

Ontario Power Generation: Nuclear Power
In this Operations website of Ontario Power Generation, the nuclear power that is used to meet "almost half of the province's electricity needs" is discussed. The site also contains links to power production maps, and information about hydroelectric power, with several additional links on other topics.

Directory of the Canadian Coalition for Nuclear Responsibility
This directory of websites contains links to over a hundred different documents, from reports and policy documents to the results of research papers and consumer opinion information--all having to do with dangers and required precautions regarding nuclear reactors.

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Question 3

Coal is often described as the “dirtiest” fossil fuel used for power generation. Name other fossil fuels that can be burned to generate power and write a short report discussing their advantages and disadvantages, or list the advantages and disadvantages in a table.

The Hidden Cost of Fossil Fuels
An appeal from the American Union of Concerned Scientists, this briefing document addresses the hidden "costs" of fossil fuels: namely, the environmental damage that manifests itself from long term fossil fuel usage in water, land and air pollution.

Natural Gas
From theInternational Council for Local
Environmental Initiatives, this website reprints an article of the Energy Educators of Ontario about natural gas. It explores the gas's origins, usage, and environmental impact.

The Environmental Impact of Natural Gas
This site promotes natural gas on behalf of several organizations, by addressing the environmental impact of other fuels that might be alleviated, especially with regard to air pollution.


Waste-to-Energy
This website describes the waste-to-energy process, and explains how exactly garbage can be used to power homes and industry through the process of combustion.

Future Fossil Fuels
This website belongs to the Department of Energy's Fossil Energy group of sites. Being an educational site, it provides lots of instructive material, clearly marked as being geared towards younger or older students.

Ontario Power Generation: Fossil
This Operations website of the Ontario Power Generation describes how fossil fuels are used to provide for much of Ontario's required electricity.

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Question 4

Both geothermal and solar energy have been suggested as clean and efficient alternatives to fossil fuels and atomic energy. Research and write a brief report on the practicality of one of these energy sources.

Concentrating Solar Power Technology
This website is hosted by Solarpaces.com, an international organization that is committed to increasing the commercial use of solar power technology. This webpage explains the various technologies that are in use to collect and concentrate solar radiation, and to convert it into useable energy.

Solar Energy Topics
Hosted by the U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy, this website discusses, and contains links to further information about several solar power technologies and issues.

Geothermal Energy Program
Hosted by the U.S. Department of Energy's Energy Efficiency and Renewable Energy Network, this website contains links to information about geothermal energy in general, along with links to information about their program and other web resources that are available.

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Question 5

Hydrogen power is described by some as the ideal alternative to fossil fuel combustion because the only product is water. Others argue that “dirty” energy source are used to produce hydrogen fuel, so that the pollution is just produced somewhere else. Find out how hydrogen fuel is obtained and report on the advantages and disadvantages of this alternative energy source.

Power Systems Software Development
This combustion research facility works with support from the U.S. Department of Energy's Hydrogen Program. This site describes a conceptual power park, and contains links to information about other research projects and topics.

Zero Emission: Coal to Hydrogen
Hosted by the Los Alamos National Laboratory of the University of California, this website describes strategies that are used to reduce toxic emissions from the combustion of fossil fuels. One strategy discussed in detail is that of using carbon dioxide to carbonate minerals, mimicking a process that occurs in nature.

Hydrogen... The Freedom Fuel
This website provided by the National Hydrogen Association (NHA), promotes the use of hydrogen in fuel cells, as a safer alternative to existing fuels. It contains several links, some multimedia, to further information about hydrogen.

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Section 5.6 Questions

Question 6

Every year several groups in Ontario organize for Canadian families to host children from the Chernobyl area of Ukraine. Research and report of the effects of the Chernobyl nuclear disaster, and how these Ontario communities are trying to improve life for a few survivors of the Chernobyl disaster.

Chernobyl Radiation Disaster Information
This website provides an "independent resource and information about radiation disaster." It contains several links to study pages and resource materials about Chernobyl and other radiation disasters.

Chernobyl: Ten Years on Radiological and Health Impact
Provided by the Nuclear Energy Agency, this website contains an assessment that a committee has made on the long-term impact of the Chernobyl disaster. It is quite details, and contains some useful resource links, like a glossary of terms used in the report.

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Chapter 5 Review

p. 357
Question 19

Canadians use more energy per capita than almost any other country in the world.


a. List some factors that contribute to this level of consumption.
b. Compare Canada’s energy consumption with that of another country. At the same time, compare the factors listed in a.
c. Choose one source of energy used in Canada, and research the efficiency and environmental impact of our use of this type of energy.
d. Write a short opinion piece on whether it is morally appropriate for Canada to have the present level of energy consumption.

Canada Analysis Brief
The Energy Information Administration (EIA) gathers official energy statistics for the U.S. Government. This website contains its report on Canada in terms of energy production, use, and export.

Canada: Data and Forecasts
The U.S. Department of Energy's E.I.A. herein provides links to important data about Canada's energy status, as well as forecasts of Canada's future in terms of energy.

Lower Energy Consumption
National Research Council Canada hosts this web page as part of its "Design for Environment Guide." This site explains why a strategy of reducing consumption is endorsed, and contains links to other parts of the guide that explain Canada and energy in terms of the "overall picture."

 

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