True/False
Indicate whether the
sentence or statement is true or false.
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1. |
Electrolytic cells are based on nonspontaneous reactions and have
a negative cell potential.
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2. |
Reduction occurs at the anode and oxidation occurs at the cathode
in an electrolytic cell.
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3. |
Electrolytic cells generally have a single electrolyte so they
are really half-cells with the power supply serving as the other half-cell.
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4. |
The
minimum potential difference for an aqueous cadmium sulfate cell with
inert electrodes is 1.63 V.
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5. |
The
charge transferred in a cell is directly proportional to both the current
and the time.
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6. |
The
mass of a nonmetal formed at the anode in an electrolytic cell is directly
related to the amount of electrons transferred at the electrode.
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7. |
If
you want to deposit twice a given mass of silver in an electrolytic
cell, then you must use twice the current for double the time.
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Multiple Choice
Identify
the letter of the choice that best completes the statement or answers
the question.
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8. |
In
an electrolytic cell, electrons are transferred through the
a. |
solution
from the anode to the cathode. |
b. |
solution from the cathode to the anode. |
c. |
porous barrier from the cathode to the anode. |
d. |
external wire from the cathode to the anode. |
e. |
external wire from the anode to the cathode. |
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9. |
Oxidation and reduction half-reactions occur
a. |
at
the surface of an electrode. |
b. |
in the power supply. |
c. |
in
the salt bridge. |
d. |
where the wire connects to the electrode. |
e. |
at the porous barrier. |
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10. |
In
an electrolytic cell, the strongest oxidizing agent reacts at the
a. |
anode
and undergoes an oxidation. |
b. |
cathode and undergoes a reduction. |
c. |
anode
and gains electrons. |
d. |
cathode and loses electrons. |
e. |
porous
barrier and transfers electrons. |
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11. |
If
we assume standard conditions, what is the cell potential for the cell
Pt(s)
| ZnBr2(aq) | Pt(s)?
a. |
+1.83 V |
b. |
+0.31
V |
c. |
-0.07
V |
d. |
-1.83V |
e. |
-2.06V |
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12. |
What
are the products obtained at the electrodes in the following cell with
a small potential difference applied?
Sn(s) | Sn(NO3)2(aq)
| Sn(s)
| |
cathode |
anode |
a |
Sn2+(aq) |
Sn4+(aq) |
b |
Sn(s) |
Sn2+(aq) |
c |
H2(g), OH-(aq) |
O2(g), H+(aq) |
d |
NO2(g), H2O(l) |
Sn2+(aq) |
e |
Sn4+(aq) |
Sn2+(aq) |
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13. |
The
Faraday constant relates
a. |
charge and current. |
b. |
current
and time. |
c. |
time and mass. |
d. |
mass
and charge of electrons. |
e. |
charge and amount of electrons. |
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14. |
In
the electrolysis of aqueous potassium hydroxide with inert electrodes,
the product(s) at the anode will be
a. |
O2(g), H+(aq) |
b. |
K(s) |
c. |
O2(g), H2O(l) |
d. |
H2(g), OH-(aq) |
e. |
KOH(s) |
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15. |
The
mass of the gas produced at the anode in the electrolysis of aqueous
potassium hydroxide using 5.9 A of current for 22 min is
a. |
0.65 g. |
b. |
0.32
g. |
c. |
0.081
g. |
d. |
0.020
g. |
e. |
0.017
g |
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16. |
Electrolytic cells used in industrial processes may do all of the
following except
a. |
produce
elements. |
b. |
refine metals. |
c. |
plate
metals. |
d. |
produce electricity. |
e. |
act
as cathodic protectors. |
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