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Alberta Chemistry 30

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Unit 5 - Organic Chemistry

Unit 6 - Chemical Energy

Unit 7 Electrochemistry

Unit 8 Chemical Equilibrium Focusing on Acid-Base Systems

Chapter 14 Electrochemical Cells

Section 14.1 Technology of Cells and Batteries

Web Activity: Canadian Achievers-Lewis Urry (page 69)

After graduating in chemical engineering from the University of Toronto in 1950, Lewis Urry went to work for Eveready Battery Company where he developed the first practical, long-life electric cell. Born in 1927 in Ontario , Urry died on October 19, 2004 .

  1. Identify the unique feature in Urry's cell ("battery").
  2. List three familiar devices that depend on the alkaline cell.
  3. Name one other cell developed by Urry.

Click "Run " to view an animation of the reactions in an alkaline cell.

Case Study: The Ballard Fuel Cell (page 70)

Question 2

One solution to the hydrogen storage problem is to make hydrogen as it is needed using a reformer. Research how reformers can be used to produce hydrogen.

Where Does Hydrogen Come From?
This "How Stuff Works" website different sources of hydrogen. There is also a link to an explanation about the technology of reformers.

Question 3

Iceland has ambitious plans to be the first nation to replace all its use of fossil fuels with "clean" hydrogen.

Research how Iceland plans to produce the hydrogen it will need.

Iceland's Hydrogen-Filling Station
This USA Today site contains an article from 2003 reporting on the opening of Iceland's first hydrogen-filling station.

Powering Iceland with Hydrogen
This 2005 article looks at Iceland's goal of becoming a hydrogen economy.  

Section 14.1 Questions (page 71)

Question 9

Most people associate technological development with "progress" in Western societies and think that technology transfer to Aboriginal peoples only occurs in one direction. In fact, although not often recognized and valued, there has been significant technology transfer from Aboriginal peoples to Western society. Summarize several examples of significant Aboriginal technological knowledge that was transferred to early European settlers. What area is still a significant source of technological transfer from Aboriginal to Western societies? Why is this an area of dispute?

Aboriginal Technology
This site discusses several examples of Aboriginal technological knowledge that have been transferred to early European settlers.

Question 10

Portable electronic devices can be found everywhere. Laptop computers, cellular telephones, mobile radios,

cordless phones, portable disc and MP3 players, and digital cameras all require an electric cell.

(a) What are some of the requirements for cells used in these applications?

(b) Why are some rechargeable batteries used in various portable devices supposed to be totally "drained" (discharged) before recharging?

Tips for Rechargeable Batteries
This website explains the difference between nickel-cadmium and lead acid batteries. It also provides tips for obtaining the best possible performance from these batteries.

The World of Rechargeable Batteries
This corporate website explains the difference between a few common rechargeable batteries, focusing especially on "discharge" characteristics. There are links to answers to questions about rechargeable batteries.

Cordless Phones and Rechargeable Batteries
This online telecom resource site is devoted exclusively to discussion of rechargeable batteries for cordless phones.

Question 11

People whose heart occasionally beats too slowly or too quickly often have pacemakers to keep their hearts beating regularly. Pacemakers use a battery for electric power. What kind of battery is commonly used today? How long does it last? How does the doctor know when the battery is nearing the end of its life and needs to be replaced? Why are rechargeable batteries generally not used?

The History of the Pacemaker
This corporate website covers the evolution of the pacemaker, from the earliest "external" pacemakers of the 1950s to the computer-like models of the new millennium.

What Is a Pacemaker?
This site addresses some of the most frequently asked questions about pacemakers, such as how they work, how they are implanted, and whether pacemaker patients are safe around electrical devices.

Pacemakers and Batteries
This website by Global Classroom has many questions and answers about pacemakers, including questions about what happens when the battery in a pacemaker needs to be replaced.

Question 12

Moli Energy of Maple Ridge, BC was the first company in the world to develop a commercial, rechargeable lithium - ion cell, called a Molicel. Research the characteristics and advantages of Molicels compared with other secondary cells.

Molicell Lithium Ion Cell
This corporate website provides basic information about the lithium ion cell used in industry. The advantages of the cell are discussed, and there are links to a datasheet on the cell.

The Future of the Lithium Ion Cell
This website provides a report on the lithium ion batteries produced by Nippon Moli Energy Corporation, a company that resulted after a Japanese company bought the Canadian company that developed the lithium ion cell.

The Latest on the Lithium Ion Cell
This corporate website presents a news release from January 2005 that provides details about the latest lithium ion cell.

Question 13

Plastic batteries were the dream of the 1980s, the disappointment of the 1990s, and the subject of the 2000 Nobel Prize for Chemistry. Now it appears that some commercial products will eventually result from the research and development invested in plastic batteries. Briefly describe the electrodes and electrolyte for a plastic battery. How is this battery similar to and different from an ordinary battery? What are some advantages and disadvantages?

The Plastic Battery
This article describes a technological development made by scientists at Johns Hopkins University. The "plastic" battery is described, and its many advantages and potential uses are mentioned.

Alan MacDiarmid
Along with a link to many additional resources, this website of the Office of Scientific and Technical Information discusses Alan MacDiarmid (Nobel Prize Winner in 2000) and his role in developing cells from polymers.

Section 14.2 Voltaic Cells

Web Activity: Analyzing Standard Voltaic Cells (page 80)

In this computer simulation, SIR Volta, you will construct many different voltaic cells under standard conditions using ten different half-cells, and then analyze their components and processes. You will need to refer to the redox table in Appendix G to make your predictions.

  1. Click "Run" to start the simulation.
  2. On the main program screen, click "V: Function" from the menu at the top left.
  3. Choose one half-cell from the list provided by clicking on it and then click the electrode in the diagram. Repeat for the second half-cell.
  4. The circled question marks that appear are hidden answers. (Ignore the "current" label and focus only on "electrons.")
  5. Using the definitions and rules for voltaic cells, and using the redox table, predict each of the component labels and processes.
  6. Click on the corresponding circled question marks to reveal the answers and check your predictions.
    Note: The voltmeter orientation is fixed. If the cell potential is negative, reverse the half-cells.

WEBLINK to SIR Volta: Voltaic Cells- coming soon

Biology Connection: Reduction Potentials (page 83)

Career Connection: Materials Engineering Technologist (page 86)

How does materials engineering relate to corrosion? Research the entrance requirements, job prospects, and typical salaries for technologists in this field.

Materials Engineering Technologist
Alberta Occupational Profiles describes the job and the necessary training. Try "Search by Title" and the relevant job title.

Materials Engineering Technology
The Northern Alberta Institute of Technology offers a Materials Engineering Technology program. This Web site describes the program, entrance requirements, and much more information.

Web Activity: Galvanizing Steel (page 87)

In this computer simulation, you will learn about the steps involved in one type of galvanizing process.

  1. Describe the method and purpose of the four main steps of the process.
  2. Evaluate the corrosion resistance of a galvanized pipe compared with a painted pipe.

Click " Run " to start the animation.

Caustic cleaning and rinsing [In the 1 st & 2 nd containers]

Steel is immersed in a basic solution to remove organic material such as grease and dirt.

Pickling and rinsing [In the 3 rd & 4 th containers]

Steel is immersed in an acid bath (hydrochloric or sulfuric acids) to remove mill scale and rust.

Flux solution [In the 5 th container]

The flux solution contains chemicals that promote a surface reaction between the steel and zinc and retard further oxidation of the steel.

Molten Zinc bath (Galvanizing) [In the 6 th container]

The very clean steel is lowered into molten zinc at about 450 °C. The surface of the steel reacts with the zinc to form zinc-iron intermetallic compounds and an outer layer of pure zinc.]

The following animation compares the corrosion resistance of a galvanized pipe with a painted pipe over a period of thirty years. Click " Run " to start the animation.

Section 14.2 Questions (pages 87-88)

Question 12

A zinc wire is connected to and buried with a pipeline when it is built (Figure 20).

(a) Why is this done? Include a brief description of the principles involved.

(b) Is this the only type of corrosion protection used with major pipelines?

(c) Discuss the environmental and safety issues associated with protecting and also not protecting pipelines.

Pipeline Corrosion Protection
This corporate website contains links to other pages with information about the various products available to protect pipelines from corrosion.

Controlling Pipeline Corrosion
This website is provided by NACE, the National Association of Corrosion Engineers. In this web page, they describe the various forms of protection available for preventing pipeline corrosion: coatings and linings, cathodic protection, materials selection, and corrosion inhibitors.

Cathodic Protection Systems
This corporate website explains the services of an Australian company that protects various industries (telecommunications, oil, water, etc.) from damage due to corrosion in a variety of projects.

One Consequence of Inadequate Pipeline Corrosion Protection This press release from the U.S. National Transportation Safety Board states that a pipeline rupture that led to two deaths was caused by a company's negligence in providing adequate corrosion protection for the pipeline.

Section 14.3 Electrolytic Cells

Web Activity: Downs Cells and Hall-Héroult Cells (page 98)

In this computer simulation, SIR Faraday, you can make and test predictions about the components and processes in two important industrial cells.

  1. Click "Run" to start the simulation.
  2. Click on "Downs Cell (Function)" on the main screen or on the menu.
  3. The circled question marks that appear are hidden answers.
  4. Using the definitions and rules for electrolytic cells, predict each of the component labels and processes.
  5. Click on the corresponding circled question marks to reveal the answers and test your predictions.
  6. You can see a simple simulation of the reactions by double-clicking the ion nearest each electrode. Double-clicking any of the other ions shows the direction in which they move.
  7. Repeat steps 2 to 6 using "Hall Cell (Function)." Notice that the anode half-reaction includes the oxidation of the carbon electrode.

WEBLINK to SIR Faraday- coming soon

Career Connection: Chemical Technician (page 100)

Chemical technicians may work closely with scientists and engineers studying electroplating processes. What education and training is required for this job? Outline some current job opportunities in this area, including typical salaries.

Chemical Technician
This article provides information about a career as a chemical technician.

The Future for Chemical Technicians
This article discusses future job prospects for chemical technicians. It also describes the education requirements and the job responsibilities.

Laboratory Technicians
This site describes the duties of a laboratory technician. It also describes the skills and education that a laboratory technician requires, the work environment, as well as links to other sites related to a career as a laboratory technician.

Section 14.3 Questions (page 101)

Question 14

(c) German silver does not contain any silver metal. Why is it called German silver? Why is it a very useful alloy?

German Silver
This site explains what "German silver" is, how it got its name, and why it is extensively used.

Question 17

The one-dollar coin, or the loonie replaced the one-dollar bill, which typically wore out in the space of a few months. Sherritt Gordon of Fort Saskatchewan, Alberta developed a unique process for plating the loonie coin.

(a) Research the production and composition of the loonie.

(b) What is the golden "aureate" finish on the loonie? Describe the materials and process for producing this finish.

(c) Why did the coin end up with a loon stamped on it?

The Loonie
This Wikipedia site explains the history of the loonie.

The Chemistry of the Loonie
This site looks at the chemistry behind the making of the Canadian dollar coin.

Question 19

Electroplating industries produce considerable waste that is expensive to manage and an environmental hazard if not treated properly. List four different types of electroplating waste, including potential hazards. Describe some ways that companies reduce, recover, and treat electroplating wastes.

Electroplating Wastes
This website is sponsored by the U.S. state of Illinois' Environmental Protection Agency. It provides information for companies and industries involved in electroplating, giving them tips on the laws that apply to them, as well as hints in reducing and preventing pollution.

Section 14.4 Cell Stoichiometry

Web Activity: Electrolytic Cell Stoichiometry (page 107)

In this activity, you perform calculations that are similar to calculations done by scientists and engineers when designing and monitoring an industrial cell.

  1. Click on "Downs Cell (Yield)".
  2. Click the dimmed "No" in both "Show Na?" and "Show Cl 2 ?" boxes. Leave the current and clock boxes with "Yes" highlighted.
  3. Click the "Start" button on the main menu.
  4. Let the clock run for a simulated time of 15-20 min and then click "Pause."
  5. Use the sodium half-reaction equation together with the given current and time to predict the mass of sodium metal that should form.
  6. Click the blank box for "Mass of Sodium Produced" to reveal the answer and test your prediction.
  7. (Optional) Repeat calculations for the volume of chlorine gas produced (using the ideal gas law).
  8. Repeat steps 1 to 7 using "Halls Cell (Yield)" and the corresponding cathode and anode products.
  9. For each cell, you can repeat this exercise by hiding and then predicting either the current or the time if the mass is set to display.

WEBLINK to SIR Faraday- coming soon

Unit 7 Review (pages 115-119)

Question 52

Battery technology is a very active area of research. One proposal that shows some promise is a vanadium redox flow cell, also known as the All Vanadium Redox Battery. Describe the general construction of this battery, including electrodes, electrolytes, porous boundary, and external tanks. What redox reactions occur at the electrodes within this cell? List some unique aspects of this technology, as well as some advantages and proposed uses.

Nickel-Metal Hydride (NiMH) Batteries
This Wikipedia site explains the chemistry of the nickel-metal hydride (NiMH) battery.

Evaluating the Nickel-Metal Hydride Battery
This site looks at the advantages and the limitations of the nickel-metal hydride (NiMH) battery.

Question 53

(c) Research and list some of the technological, economic, and environmental considerations involved in evaluating the NiMH battery.

The Vanadium Redox Battery
This website is provided by the University of New South Wales in Australia, where the vanadium redox battery was invented. The entire site is devoted to this particular battery, with several links pointing to different types of information about it. A picture gallery is also provided.

Information on the Vanadium Battery
This private website contains several links to various websites, all of which have something to do with vanadium batteries. There is an especially large amount of information on worldwide patents that are held on the battery, and other issues of interest to corporations.

Question 55

The Alberta government is considering making carbon monoxide detectors mandatory for new residential homes as is done in Ontario. What are the sources and the health effects of carbon monoxide? Briefly describe how a modern CO detector works including the reaction equations and catalyst involved. Should CO detectors be required in all homes? Justify your opinion.

The Health Effects of Carbon Monoxide
This site discusses the sources of carbon monoxide, as well as the effects that carbon monoxide has on health. There is also a link to a report that describes the treatment of carbon monoxide poisoning.

Carbon Monoxide Detectors
This site describes how carbon monoxide detectors work.

Question 56

Sludge and wastewater from electroplating processes contain chromium, copper, gold, nickel, and silver, as well as cyanide ions. Sending these metals to landfill or discharging them in wastewater, instead of recycling them, is detrimental to the environment and wasteful of energy. Technologies are being developed to separate and purify these metals including precipitation, electrolysis, and reverse osmosis. Research one technology designed to reduce the environmental impact of the electroplating industry, and prepare a short presentation on how it works.

Recycling Water from Electroplating Processes
This corporate website describes recommendations regarding various methods that are available for recycling water used in electroplating processes. It discusses the advantages and disadvantages of four types of systems.

Hexavalent Chromium Waste Treatment
This corporate resource document describes a method available to dispose of hexavalent chromium waste, a carcinogenic chemical that became infamous after the wide coverage it received in the 2000 movie, Erin Brockovich .